From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. Selection of stainless steels for handling sodium hydroxide. Caustic caustic soda is sometimes used in water treatment systems. This chapter addresses the cracking behavior of nickel alloys in industries such as chemical process, nuclear power generation and in oil and gas exploration and production. Thus, this study investigated the possibility of corrosion damage to turbine components due to acidified, early condensates containing acetic acid, which is a common impurity in steam cycle. Mar 27, 2002 the first reported instance of stress corrosion cracking of titanium was in red fuming nitric acid. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain.
Choose from 96 different sets of caustic flashcards on quizlet. In heat exchangers, not only is the process stream important, but also the cooling medium must be taken into account. In each failure analysis case study, the cracking is characterized using various metallurgical laboratory techniques, including metallography and. May 08, 2020 api 571 damage mechanisms affecting fixed equipment in the refining industry for api 571 corrosion and materials professional certification. Caustic stress corrosion cracking of steels is one of the oldest known forms of scc, dating back to the days of the early steam locomotives, when it was responsible for countless explosions of riveted boilers trethewey et al. Tube od surfaces experience thermal fatigue stress cycles which can occur from normal shedding of slag, sootblowing, or from cyclic operation of the boiler.
Under these conditions, nickel alloy c22 is recommended. The stress corrosion cracking in expanded parts of stainless steel heat exchangers and its prevention were studied. Discussion caustic stress corrosion cracking of steels is one of the oldest known forms of scc, dating back to the days of the early steam locomotives, when it was responsible for countless explosions of riveted boilers trethewey et al. As a general rule, the resistance to caustic solutions increases with increasing nickel content. Stress corrosion cracking scc is the formation and growth of crack through materials subjected to tensile stress and a specific corrosive medium. Nace sp0403 avoiding caustic stress corrosion cracking. Stress corrosion or stressassisted corrosion cracks are typically branched with numerous small secondary cracks associated with the main fracture area. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic. Crazing can be induced at moderate to high stress levels by low molecular weight hydrocarbons.
Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Pdf caustic soda is used in several refinery processes. Stress corrosion cracking scc or environmentally induced cracking. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. Caustic stress corrosion cracking inspectioneering.
Caustic cracking definition caustic cracking is a form of stress corrosion. Stress corrosion cracking international institute of. Further progress is then a process alternating between corrosion and mechanical cracking until the material fails completely. Concentration can occur as a result of alternating wet and dry conditions, localized hot spots and or temperature steam out. Other higher nickel stainless alloys like alloy 20, 800 and 825 also resist caustic corrosion and caustic cracking better than the 300 series stainless steels. Pdf stress corrosion cracking of stainless steel components. Citeseerx document details isaac councill, lee giles, pradeep teregowda. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Caustic scc is driven by tensile stress, susceptible material and concentration of caustic. Alloy b2 is damaged by intergranular stress corrosion cracking in the heat affected region when subjected to organic solvents comprising of sulfuric acid at 120oc. Corrosion behaviour of type 316l stainless steel in hot. Improved resistance to caustic stress corrosion cracking can be given to inconel by heat treating it at 620 o c to 705 o c, depending upon prior solution treating temperature. Stress corrosion cracking scc is the formation and growth of crack. Amine stress corrosion cracking amine scc or amine cracking.
Nace sp0403 avoiding caustic stress corrosion cracking of. The material performance in these environments is governed by the stability of the passive surface film, which develops as a function of alloy microstructure. The effect of acetic acid on the stress corrosion cracking. The corrosion of stainless steel in hot caustic environment has been the subject of a number of investigations, typically with a focus on kraft pulping liquors 1,2,3,4,5,6,7,8,9,10,11.
At higher temperatures, stress corrosion cracking and corrosion fatigue are possible. The mechanism of scc is shown as a simple representation in figure 1. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Oct 15, 2017 caustic corrosion is a type of corrosion that occurs in metal equipment e. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Stress corrosion cracking scc of nickelbased alloys.
Stress corrosion cracking scc of type 304 stainless steel in 20n caustic solution was investigated in the presence of chromate ions, using the constant strain rate 10sup 710sup 5s technique. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment it is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel. Here, cracking was mainly intergranular but the phenomenon only occurred under anhydrous conditions, the presence of as little as 1. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. Stainless steels are more resistant to general corrosion compared with carbon steel. Modified streicher and 288 c 550 f electrochemical caustic stress corrosion tests were performed on alloy 600 to determine the relationship between acid intergranular attack susceptibility and caustic stress corrosion cracking scc susceptibility. Products such as acetone and xylene may cause stress cracking even at very low stress. Alloyenvironment combinations exhibiting stress corrosion cracking. Caustic stress corrosion cracking, also referred to as caustic embrittlement, is a form of degradation that is caused when a component operates in a caustic environment. Industrial experience on the caustic cracking of stainless. The area of risk in sodium hydroxide is shown on the iso corrosion diagram by the area bounded by a green line. As with other forms of stress corrosion cracking, caustic cracking will.
Molybdenum provides resistance to reducing acids, in particular to hydrochloric acid. Under very high stress and elevated temperatures these materials can suffer from caustic cracking. Caustic stress corrosion cracking was first encountered in the operation of riveted steam boilers. Environments that may cause stress corrosion cracking in nickel alloys include hot caustic solutions, high temperature water and hot and wet hydrofluoric acid. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic stainless steel equipment. Stress corrosion cracking is the growth of crack formation in a corrosive environment. In many applications, cs is the material of choice for equipment and piping in caustic service.
Caustic stress corrosion cracking occurs at higher temperatures than chloride stress corrosion cracking. Natural conditions for caustic cracking of a mild steel. The first reported instance of stress corrosion cracking of titanium was in red fuming nitric acid. Two examples of stress corrosion cracking scc in refinery equipment are presented to highlight the lessons learned to prevent recurrence of such failures. It can lead to unexpected sudden failure of normally ductile metals.
Results confirmed that the chromate ions act as an oxidizing inhibitor and prevent caustic cracking. Sp04032015, avoiding caustic stress corrosion cracking. Standard practice for evaluating stresscorrosioncracking. Concentrated water with other aggressive agents such as caustic and chlorides leaked through the. Pdf stress corrosion cracking scc of nickelbased alloys. Model test blocks of the exchangers were constructed with tubes expanded by. During removal of deposits in the inhibited acid solution, a hydrogen sulfide. The more susceptible areas are around nozzles and in or next to.
So, lack of pwht will increase susceptibility, mostly from residual tensile stresses, and not just hardness. The chemical environment that causes scc for a given alloy. It occurs where a combination of hightensile stresses and a corrosive fluid are present. It is one of the most prevalent afflictions in the industry and one of many environmental cracking mechanisms that typically occur in carbon steel equipment, but it can also afflict low alloy and austenitic. The stress corrosion cracking behavior in caustic solutions 200 gl sodium hydroxide, 10 gl sodium chloride of three austenitic 18cr10ni2. Caustic stress corrosion cracking scc is the most serious form of corrosion that can occur in a continuous digester and has resulted in the catastrophic failure of a continuous digester. There is caustic stress corrosion cracking when carbon steel is exposed to concentrated caustic solution. Caustic corrosion an overview sciencedirect topics. Cast iron or steel are adequate for low temperature use, particularly if iron contamination of the product is not an issue. Carbon steel in caustic service corrosion engineering eng. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. For caustic stress corrosion cracking, what are some concentration mechanisms.
The test may not be relevant to stresscorrosion cracking in polythionic acid or caustic environments. Corrosion, stress corrosion cracking, and electrochemistry of. Alloy 20 is an excellent option when chloride stress corrosion cracking is an issue and resists pitting and crevice corrosion. Boiler water could easily flow into the crevices which existed under the. Although stress corrosion cracking of duplex stainless steels in chloride solution has been investigated and well documented in the literature but the scc mechanisms for dss in caustic solutions were not known. Stress corrosion cracking the international institute of. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. Caustic stress corrosion cracking caustic embrittlement. Risk of stress corrosion cracking attack caustic stress corrosion cracking occurs at higher temperatures than chloride stress corrosion cracking which can occur at temperatures as low as 60 degc. Nickel alloy c22 should be used in all caustic applications in. Metalenvironment combinations susceptible to cracking are specific.
Stress corrosion cracking issues in syngas plants that may. However, high corrosion rates will occur if tantalum is used in caustic applications such as sodium hydroxide, even at room temperature. Stress corrosion cracking and component failure table 1. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. This standard incorporates the findings of that survey as they apply to refinery applications.
Alloy 400 n04400 and alloy 600 n06600 also have excellent stress corrosion resistance. The chemical environment that causes scc for a given alloy is often one which is only mildly corrosive to the metal. Polythionic acid stress corrosion cracking pascc is a type of intergranular stress corrosion that affects sensitized stainless steels in refineries processing feedstocks containing sulphur. This phenomenon mostly occurs in boilers where caustic soda. Mill annealed and solution annealed materials with and without a subsequent 621 c 1150 f. Anot her example of caustic leakage and white salt is on the surface of the caustic storage tank s outlet nozzle caused by caustic stress corrosion cracking. Corrosion by caustic sodium or potassium hydroxide at all concentrations is easily handled at room temperature with a variety of metals and alloys, including carbon steels.
Consequently, caustic corrosion called caustic embrittlement more accurately, a specific kind of stress corrosion cracking was engendered on the carbon steel tubes under both concentrated naoh and tensile stress because the operational pressure of the tube side was larger than the shell side, and corrosion products including na 3 feo 3, na. Mechanisms of stresscorrosion cracking asm international. The following conditions are necessary for this type of cracking to occur. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Aug 01, 2018 caustic cracking is a form of stress corrosion cracking most frequently encountered in carbon steels or ironchromiumnickel alloys that are exposed to concentrated hydroxide solutions at temperatures of 482f 250c. Scc affects mainly welds in the impregnation zone or in. The useful safe limit of carbon steel is approximately 150 o f65 o c, both with regard to caustic stress corrosion cracking cscc and corrosion. This resistance is due to the inert and protective character of the aluminium oxide. However, stress corrosion cracking continues to be a problem in aging plants and must be considered. Uk aluminium industry fact sheet 2 aluminium and corrosion. A guide to chemical resistance of polycarbonate sheet. Relationship between acid intergranular corrosion and. The effects of acetic acid on the stress corrosion cracking scc susceptibility of astm a470471 turbine diskrotor steels 3. Stress corrosion cracking of duplex stainless steels in.
Thermal cycling, in addition to subjecting the material to cyclic stress, can initiate cracking of the less elastic external tube scales and expose the tube base material to repeated corrosion. Fabrication and heat treatment alloy 20 can be formed by either hotworking or coldwork using traditional methods. Apart from the classically known hydroxide and nitrate media, stress corrosion cracking of such steels has been reported in a number of other environments, namely aqueous chloride, carbonate, phosphate, ammonia, coco 2h 2 o, high purity water containing oxygen, fuel ethanol and several. This means that all environments do not cause scc on all of the alloys. Carbon steel in caustic service corrosion engineering. Stress corrosion cracking behavior of nickel base alloys. The important general point is that those environments that cause stress corrosion are frequently highly specific to the particular. Microstructural changes during fabrication processes affect the overall scc susceptibility of these steels in caustic solutions. Avoiding caustic stress corrosion cracking of carbon steel refinery equipment and piping this standard practice establishes guidelines to avoid caustic scc of cs refinery equipment and piping. Chromium induces passivation in oxidizing acids, as it does in the stainless steels. Here, cracking was mainly intergranular but the phenomenon only occurred under anhydrous conditions, the presence of as little.
Scc is the brittle cracking of a metal due to the result of combined effects from localized corrosion and tensile stress. Feb 22, 2001 chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. Aluminium and corrosion 1 introduction although aluminium is a very reactive metal with a high affinity for oxygen, the metal is highly resistant to most environments and to a great variety of chemical agents. It is a form of stress corrosion cracking characterized by sur which materials are susceptible to caus carbon, low alloy steels and 300ss are susceptible. These alloys can be candidates for service in caustic exposure when corrosion from cooling waters is a concern. Stress corrosion cracking caustic embrittlement of super heater. Some mechanisms, such as a slight leak, must be present to allow the boiler water to concentrate on the. It has been shown that, for some materials, fine pitting is needed to start the activity. Stress corrosion cracking scc in low and medium strength. Stress corrosion cracking is induced by polythionic acid.
Relationship between acid intergranular corrosion and caustic. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking. It becomes increasingly more corrosive with increasing temperature and concentration. In the hydroiodic acid at temperatures exceeding 177oc, alloy b2 was sensitive to transgranular stress corrosion cracking. Cracks occur at the nozzle to shell a nd flange to nozzle which is a high stress area and discontinuous api rp 572. Thus, the addition of caustic soda to boiler feed waters to reduce the corrosiveness of the latter towards mild steel can result in the form of stress corrosion frequently referred to as caustic cracking. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be. Failure was attributed to caustic induced cracking at the highly stressed regions near and under the rivets.
Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. Stress corrosion cracking issues in syngas plants that may be. Despite the extensive qualification of inconel for specific applications, a number of corrosion problems have arisen with inconel tubing. These alloys can however suffer from caustic stress corrosion cracking at caustic concentrations above 70% at temperatures above 290crmo c 550f. These boilers were found to fail on occasion along riveted seams.
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